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Add the chocolate chips, coconut milk, Chinese five spice, and salt to a heat-safe bowl.
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Put the bowl over a small/medium saucepan with water over low heat (this is a double boiler).
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Stirring the mixture as the water warms up and starts to gently melt the chocolate.
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Incorporate all ingredients together well as the chocolate melts.
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Remove from heat as soon as melted together.
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Put the bowl in the fridge and allow to set, about 2 hours.
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The chocolate should be set.
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Put the cacao powder onto a plate.
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Using a small spoon, scrape up about 1 tablespoon of the mixture and roll into a ball by rolling it in between your hands.
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Drop the truffle onto the plate with the cacao powder and roll to coat.
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Repeat the process until you have used the entire chocolate mixture.
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Store the truffles in a dish in the fridge.